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On the miscibility gap of Cu-Ni system

2016/11/21 by Yusuke Iguchi, Gabor Katona, Iguchi, Yusuke +11 · 1 citation
Engineering · Materials Science · Physics and Astronomy · #Advanced Materials Characterization Techniques #FOS: Physical sciences #Materials Science (cond-mat.mtrl-sci) #Metal and Thin Film Mechanics #Metallurgical and Alloy Processes #cond-mat.mtrl-sci

paper · pdf · doi:10.48550/arxiv.1611.07068

10 pages as preprint version, 3 figures, and we will have also "Supplementary Material" with 7 pages and 3 figures, which is contained in zipped source file. You can download from right, "Download > Other formats > Source > Download source"

openalex publication_date 2016/11/21 · arxiv created 2016/11/28 · arxiv updated 2016/11/29 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

The existence of the miscibility gap in the Cu-Ni system has been an issue in both computational and experimental discussions for half a century [Chakrabarti et al., Phase diagrams of binary nickel alloys, ASM, 1991]. Here we propose a new miscibility gap in the Cu-Ni system measured in nano-layered thin films by Secondary Neutral Mass Spectrometry. The maximum of the symmetrical miscibility curve is around 800~K at Cu50%Ni50%. To our best knowledge, this is the first experiment determining the miscibility from the measurement of the atomic fraction of Copper and Nickel in the whole composition range. Needless to say that Ni, Cu and its alloys are important in various fields, accordingly this result affects different areas to understand materials sciences.

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