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Contact effects on transport in magnetite, an archetypal correlated transition metal oxide

2010/11/29 by Alexandra Fursina, A. A. Fursina, R. G. S. Sofin +7
Biochemistry, Genetics and Molecular Biology · Energy · Environmental Science · Physics and Astronomy · #FOS: Physical sciences #Geomagnetism and Paleomagnetism Studies #Iron oxide chemistry and applications #Mesoscale and Nanoscale Physics (cond-mat.mes-hall) #Minerals Flotation and Separation Techniques #Strongly Correlated Electrons (cond-mat.str-el) #cond-mat.mes-hall #cond-mat.str-el

paper · pdf · doi:10.48550/arxiv.1011.6407

6 pages, 5 figures

arxiv created 2010/11/29 · openalex publication_date 2010/11/29 · arxiv updated 2010/12/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

Multiterminal measurements have typically been employed to examine electronic properties of strongly correlated electronic materials such as transition metal oxides without the influence of contact effects. In contrast, in this work we investigate the interface properties of Fe3O4 with different metals, with the contact effects providing a window on the physics at work in the correlated oxide. Contact resistances are determined by means of four-terminal electrical measurements as a function of source voltage and temperature. Contact resistances vary systematically with the work function of the electrode metal, ϕ(M), M=Cu, Au and Pt, with higher work function yielding lower contact resistance. This trend and the observation that contact resistances are directly proportional to the Fe3O4 resistivity are consistent with modeling the oxide as an effective p-type semiconductor with hopping transport. The jumps in contact resistance values at the bias-driven insulator-metal transition have a similar trend with ϕ(M), consistent with the transition mechanism of charge gap closure by electric field.

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