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Limiting flux in quantum thermodynamics

2023/11/22 by Domingos S. P. Salazar, Salazar, Domingos S. P.
Physics and Astronomy · #Advanced Thermodynamics and Statistical Mechanics #Spectroscopy and Quantum Chemical Studies #Quantum many-body systems

paper · pdf · doi:10.48550/arxiv.2311.13536

Abstract

In quantum systems, entropy production is typically defined as the quantum relative entropy between two states. This definition provides an upper bound for any flux (of particles, energy, entropy, etc.) of bounded observables, which proves especially useful near equilibrium. However, this bound tends to be irrelevant in general nonequilibrium situations. We propose a new upper bound for such fluxes in terms of quantum relative entropy, applicable even far from equilibrium and in the strong coupling regime. Additionally, we compare this bound with Monte Carlo simulations of random qubits with coherence, as well as with a model of two interacting nuclear spins.

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