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Contributions of Repulsive and Attractive Interactions to Nematic Order

2018/06/28 by Peter Palffy‐Muhoray, Jamie M. Taylor, Palffy-Muhoray, Peter +5
Materials Science · Physics and Astronomy · #FOS: Physical sciences #Liquid Crystal Research Advancements #Material Dynamics and Properties #Soft Condensed Matter (cond-mat.soft) #Theoretical and Computational Physics

paper · pdf · doi:10.48550/arxiv.1806.10738

openalex publication_date 2018/06/28 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

Both repulsive and attractive molecular interactions can be used to explain the onset of nematic order. The object of this paper is to combine these two nematogenic molecular interactions in a unified theory. This attempt is not unprecedented; what is perhaps new is the focus on the understanding of nematics in the high density limit. There, the orientational probability distribution is shown to exhibit a unique feature: it has compact support on configuration space. As attractive interactions are turned on, the behavior changes, and at a critical attractive interaction strength, thermotropic behavior of the Maier-Saupe type is attained.

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