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In aqua electrochemistry probed by XPEEM: experimental setup, examples,\n and challenges

2018/02/07 by Slavomír Nemšák, Nemšák, Slavomír, Evgheni Strelcov +19 · 1 citation
Chemistry · Energy · Physics and Astronomy · #Electrochemical Analysis and Applications #FOS: Physical sciences #Iron oxide chemistry and applications #Materials Science (cond-mat.mtrl-sci) #Spectroscopy and Quantum Chemical Studies

paper · pdf · doi:10.48550/arxiv.1802.02545

openalex publication_date 2018/02/07 · openalex created_date 2022/10/06 · openalex updated_date 2026/07/28

Abstract

Recent developments in environmental and liquid cells equipped with electron\ntransparent graphene windows have enabled traditional surface science\nspectromicroscopy tools, such as X-ray photoelectron spectroscopy (XPS),\nphotoemission electron microscopy (PEEM), and scanning electron microscopy\n(SEM) to be applied to study solid-liquid and liquid-gas interfaces. Here, we\nfocus on the experimental implementation of PEEM to probe electrified\ngraphene-liquid interfaces using electrolyte-filled microchannel arrays as a\nnew sample platform. We demonstrate the important methodological advantage of\nthese multi-sample arrays: they enable the combination of the wide field of\nview hyperspectral imaging capabilities from PEEM with the use of powerful data\nmining algorithms to reveal spectroscopic and temporal behaviors at the level\nof the individual microsample or the entire array ensemble\n

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