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Single-molecule electroluminescence: crossover from weak to strong coupling

2025/04/18 by Andrés Bejarano, Bejarano, Andrés, Moritz Frankerl +7 · 1 voice
Physics and Astronomy · #FOS: Physical sciences #Mesoscale and Nanoscale Physics (cond-mat.mes-hall) #cond-mat.mes-hall

paper · pdf · doi:10.48550/arxiv.2504.13657

arxiv published 2025/04/18 · arxiv updated 2025/07/04

Abstract

We develop a microscopic model to investigate current-induced light emission in single-molecule tunnel junctions, where a two-level system interacts with a plasmonic field. Using the quantum master equation, we explore the transition from weak to strong plasmon-molecule coupling, identifying three distinct regimes governed by cooperativity, which quantifies the interplay between interaction strength and losses. Our findings establish a framework to detect strong coupling, unveiling resonance-dependent features in the emission spectrum and photon correlations.

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