2024/08/29 by Rüssel, Christian, Kohl, Reiner, Schaeffer, Helmut Α.
#660
paper · doi:10.34657/14249
The oxidation state of molten soda-lime-silica glass was studied by an electrochemical oxygen-sensor, based on an yttria-stabilized zirconia solid electrolyte. It is shown that the iron concentration of the glass melt influences the extent of oxygen activity variation during cooling. If the iron concentration is 0.2 mol% Fe2O3 or less, the redox ratio [Fe3+]/[Fe2+] cannot be assumed to be independent of temperature because the redox equilibrium is shifted by the reactivity of physically dissolved oxygen.