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Analytical solution of the Schrödinger equation for the hydrogen molecular ion H2+

2015/08/06 by Mitin, A. V.
#Atomic Physics (physics.atom-ph) #Chemical Physics (physics.chem-ph) #FOS: Physical sciences #Quantum Physics (quant-ph)

paper · doi:10.48550/arxiv.1508.01359

Abstract

The full analytical solution of the Schrödinger equation for the hydrogen molecular ion H2+ (special case of the quantum tree-body problem with the Coulomb interaction) is obtained first. The solution shows that the total wave function is a two-term function in the sense that it is a linear combination of the two linear independent wave functions. The two-term character of the total wave function was visualized in calculations of the total electron density of H2+ at different internuclear separations.

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