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Colloid-Polymer Mixtures Confined Between Asymmetric Walls: Simulation Evidence for an Interface Localization Transition

2006/09/18 by De Virgiliis, A., Vink, R. L. C., Horbach, J. +1
#Disordered Systems and Neural Networks (cond-mat.dis-nn) #FOS: Physical sciences #Soft Condensed Matter (cond-mat.soft)

paper · doi:10.48550/arxiv.cond-mat/0609434

Abstract

Phase separation of colloid-polymer mixtures, described by the Asakura-Oosawa (AO) model, confined in a thin slit pore is studied by grand-canonical Monte Carlo simulation. While one wall is a hard wall for both particles, at the other wall there acts an additional repulsive potential on the colloids only. Varying the strength of this potential, a crossover from capillary condensation to an interface localization transition is found. The latter occurs under conditions where in the bulk almost complete phase separation has occurred.

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