Threshold and high-frequency behavior of dipole-bound anion photodetachment

2003/03/20 by Vladislav E. Chernov, Chernov, Vladislav E., Boris A. Zon +1
Physics and Astronomy · #Chemical Physics (physics.chem-ph) #FOS: Physical sciences #physics.chem-ph

paper · pdf · doi:10.48550/arxiv.physics/0303081

4 pages, 3 figures

arxiv created 2003/03/20 · arxiv updated 2009/12/01

Abstract

An explicit analytic description is given for dipole-bound anion (DBA) as an excess electron bound to the molecular neutral due to its dipole moment. The calculated DBA photodetachment cross-section displays ∝ω^-2 behavior for large ω, in complete accordance with the experimental data [Bailey et al., J. Chem. Phys 104, 6976 (1996)]. At the threshold the photodetachment cross-section displays the Gailitis--Damburg oscillations.

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