2015/05/07 by H. H. Segnorile, Segnorile, H. H., C. E. González +3
Chemistry · Physics and Astronomy · #Molecular spectroscopy and chirality #Advanced NMR Techniques and Applications #Spectroscopy and Quantum Chemical Studies
paper · pdf · doi:10.48550/arxiv.1505.01558
New evidence is presented in favor of irreversible decoherence as the mechanism which leads an initial out-of-equilibrium state to quasi-equilibrium in nematic liquid crystals. The NMR experiment combines the Jeener-Broekaert sequence with reversal of the dipolar evolution and decoding of multiple-quantum coherences to allow visualizing the evolution of the multi-spin coherence spectra during the formation of the quasi-equilibrium states. We vary the reversion strategies and the preparation of initial states and observe that the spectra amplitude attenuate with the reversion time, and notably, that the decay is frequency selective. We interpret this effect as evidence of "eigen-selection", a signature of the occurrence of irreversible adiabatic decoherence, which indicates that the spin system in liquid crystal NMR experiments conforms an actual open quantum system.