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Open quantum system simulation of time and frequency resolved spectroscopy

2024/03/15 by Kramer, Tobias
#Biological Physics (physics.bio-ph) #FOS: Physical sciences #Quantum Physics (quant-ph)

paper · doi:10.48550/arxiv.2403.10192

Abstract

The dynamics of excitonic energy transfer in molecular complexes triggered by interaction with laser pulses offers a unique window into the underlying physical processes. The absorbed energy moves through the network of interlinked pigments and in photosynthetic complexes reaches a reaction center. The efficiency and time-scale depend not only on the excitonic couplings, but are also affected by the dissipation of energy to vibrational modes of the molecules. An open quantum system description provides a suitable tool to describe the involved processes and connects the decoherence and relaxation dynamics to measurements of the time-dependent polarization.

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