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Structural studies of thin films of semiconducting nanoparticles in\n polymer matrices

2006/07/19 by T. Di Luccio, Di Luccio, T., E. Piscopiello +6
Engineering · Materials Science · #Chalcogenide Semiconductor Thin Films #FOS: Physical sciences #Gold and Silver Nanoparticles Synthesis and Applications #Materials Science (cond-mat.mtrl-sci) #Quantum Dots Synthesis And Properties

paper · pdf · doi:10.48550/arxiv.cond-mat/0607488

openalex publication_date 2006/07/19 · openalex created_date 2022/10/03 · openalex updated_date 2026/07/28

Abstract

We deposited thin layers of CdS and ZnS nanoparticles embedded in a\nthermoplastic cyclo-olephin copolymer (COC) with elevated optical transparency\nand highly bio-compatible. The nanoparticles were obtained by thiolate\nprecursors previously dispersed in the polymer upon thermal treatment at\ntemperatures ranging between 200 and 300 Celsius degrees depending on the\ndesired size. The precursor/polymer solutions were spin coated in order to get\nthin films. The samples were mainly characterised by X-ray reflectivity (XRR)\nand by High Resolution Transmission Electron Microscopy (HRTEM) analyses. The\nHRTEM measurements showed that the nanoparticles have quasi-spherical shape\nwithout evident microstructural defects. The size of the nanoparticles depends\non the annealing temperature, e.g. at 232 Celsius degrees the size of the CdS\nnanoparticles is about 4-5 nm.\n

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