2024/01/18 by S. Müller, Muller, S., Romane Le Gal +17 · 1 citation
Physics and Astronomy · #Astronomy and Astrophysical Research #Astrophysics and Star Formation Studies #Astrophysics of Galaxies (astro-ph.GA) #FOS: Physical sciences #Galaxies: Formation, Evolution, Phenomena
paper · pdf · doi:10.48550/arxiv.2401.09975
openalex publication_date 2024/01/18 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28
We report the first interstellar identification of protonated acetylene, C2H3+, a fundamental hydrocarbon, in the z=0.89 molecular absorber toward the gravitationally lensed quasar PKS1830-211. The molecular species is identified from clear absorption features corresponding to the 212-101 (rest frequency 494.034 GHz) and 111-000 (431.316 GHz) ground-state transitions of ortho and para forms of C2H3+, respectively, in ALMA spectra toward the southwestern image of PKS1830-211, where numerous molecules, including other hydrocarbons, have already been detected. From the simple assumption of local thermodynamic equilibrium (LTE) with cosmic microwave background photons and an ortho-to-para ratio of three, we estimate a total C2H3+ column density of 2 x 1012 cm-2 and an abundance of 10-10 compared to H2. However, formation pumping could affect the population of metastable states, yielding a C2H3+ column density higher than the LTE value by a factor of a few. We explore possible routes to the formation of C2H3+, mainly connected to acetylene and methane, and find that the methane route is more likely in PDR environment. As one of the initial hydrocarbon building blocks, C2H3+ is thought to play an important role in astrochemistry, in particular in the formation of more complex organic molecules.