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Influence of Ionic strength on calcium carbonate (CaCO3) polymorphism

2012/09/14 by Taylor A. Evans, Taylor Evans, Evans, Taylor
Materials Science · Physics and Astronomy · #Calcium Carbonate Crystallization and Inhibition #FOS: Physical sciences #Materials Science (cond-mat.mtrl-sci) #cond-mat.mtrl-sci

paper · pdf · doi:10.48550/arxiv.1209.3333

5 pages, two figures

arxiv created 2012/09/14 · openalex publication_date 2012/09/14 · arxiv updated 2012/11/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

CaCO3 crystals' physical properties, such as polymorphism and hence the reflectivity and stability, are critical factors of their qualities in industrial applications. Factors such as additives and substrates that influence CaCO3 polymorphism have been intensively studied. However, the effects of ionic strength created by varying additives are seldom paid attention to. This study is analyzing how ionic strength of the growth solution influences the crystalline structure of CaCO3, by applying growth solutions containing different types of cations of varying concentrations, K+, Na+, and NH4+. This study reveals that the ionic strength plays a significant role in polymorph selection in the way that the percentage of vaterite among the precipitates increases with the concentration of ionic strength.

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