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Superconductivity in new family of Rhenium-based binary alloys: Re7X3 (X = Nb, Ta, Ti, Zr, Hf)

2024/02/12 by R. K. Kushwaha, Kushwaha, R. K., P. K. Meena +15 · 1 citation
Materials Science · Physics and Astronomy · #FOS: Physical sciences #Iron-based superconductors research #Rare-earth and actinide compounds #Superconductivity (cond-mat.supr-con) #Superconductivity in MgB2 and Alloys

paper · pdf · doi:10.48550/arxiv.2402.07580

openalex publication_date 2024/02/12 · openalex created_date 2024/02/14 · openalex updated_date 2026/07/28

Abstract

Rhenium-based superconductors have recently attracted significant interest due to their unconventional superconducting properties. In this work, we report the synthesis and properties of new superconducting Re7X3 (X = Nb, Ta, Ti, Zr, Hf) binary alloys which maintain a fixed composition of rhenium while crystallizing in centrosymmetric to non-centrosymmetric crystal structures, depending on the elements of the X site. Comprehensive structural and superconducting properties were investigated using powder x-ray diffraction, AC transport, magnetization, and specific heat measurements, and on the basis of these measurements, the superconducting phase diagram was constructed. The results suggest a complex interplay of crystal structure and the Re/X ratio, which governs the strength of spin-orbital coupling and controls the unconventional superconducting behavior in Re-based superconductors.

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