2012/11/29 by Ting Ge, Flint Pierce, Ge, Ting +7
Arts and Humanities · Physics and Astronomy · #Crafts, Textile, and Design #FOS: Physical sciences #Soft Condensed Matter (cond-mat.soft) #cond-mat.soft
paper · pdf · doi:10.48550/arxiv.1211.6796
arxiv created 2012/11/29 · openalex publication_date 2012/11/29 · arxiv updated 2012/11/30 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28
Large-scale simulations of thermal welding of polymers are performed to investigate the rise of mechanical strength at the polymer-polymer interface with the welding time. The welding process is in the core of integrating polymeric elements into devices as well as in thermal induced healing of polymers; processes that require development of interfacial strength equal to that of the bulk. Our simulations show that the interfacial strength saturates at the bulk shear strength much before polymers diffuse by their radius of gyration. Along with the strength increase, the dominant failure mode changes from chain pullout at the interface to chain scission as in the bulk. Formation of sufficient entanglements across the interface, which we track using a Primitive Path Analysis is required to arrest catastrophic chain pullout at the interface. The bulk response is not fully recovered until the density of entanglements at the interface reaches the bulk value. Moreover, the increase of interfacial strength before saturation is proportional to the number of interfacial entanglements between chains from opposite sides.