2008/06/24 by Yuri Kornyushin, Kornyushin, Yuri
Chemistry · Physics and Astronomy · #Advanced Physical and Chemical Molecular Interactions #Chemical Physics (physics.chem-ph) #FOS: Physical sciences #Quantum Physics (quant-ph) #physics.chem-ph #quant-ph
paper · pdf · doi:10.48550/arxiv.0806.3828
This paper can help to understand better the topic of kinetic energy and self-action in non-relativistic Quantum Mechanics; Russian version included
openalex publication_date 2008/06/24 · arxiv created 2009/08/07 · arxiv updated 2009/12/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28
A concept of kinetic energy in quantum mechanics is analyzed. Kinetic energy is a non-zero positive value in many cases of bound states, when a wave function is a real-valued one and there are no visible motion and flux. This can be understood, using expansion of the wave function into Fourier integral, that is, on the basis of virtual plane waves. The ground state energy of a hydrogen atom is calculated in a special way, regarding explicitly all the terms of electrostatic and kinetic energies. The correct values of the ground state energy and the radius of decay are achieved only when the electrostatic energies of the electron and the proton (self-energies) are not taken into account. This proves again that self-action should be excluded in quantum mechanics. A model of a spherical ball with uniformly distributed charge of particles is considered. It is shown that for a neutral ball (with compensated electric charge) the electrostatic energy is a non-zero negative value in this model. This occurs because the self-energy of the constituting particles should be subtracted. So it shown that the energy of the electric field does not have to be of a positive value in any imaginable problem.