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ZnO Defect Modulation for Efficient Photocatalysis

2017/10/04 by E.N. Epie, Epie, E. N., Wen‐Xin Chu +1
Energy · Materials Science · #78-05 #Advanced Photocatalysis Techniques #FOS: Physical sciences #Ga2O3 and related materials #J.2 #Materials Science (cond-mat.mtrl-sci) #ZnO doping and properties

paper · pdf · doi:10.48550/arxiv.1710.01478

openalex publication_date 2017/10/04 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

We have investigated the combined effect of low-energy self-implantation and thermal annealing on the near-surface defect concentration of ZnO single-crystals. Using ionoluminescence (IL), we demonstrate that a combination of low-energy low-fluence Zn and O ion implantation followed by annealing in Ar increases the near-surface point defect concentration in ZnO by two orders of magnitude. Point defects are known to increase the surface reactivity of ZnO, thereby improving the efficiency of ZnO photocatalytic processes such as bilirubin degredation. We hereby provide recommendations on how to improve the efficiency of ZnO-related photocatalytic processes.

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