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Approach to equilibrium for a particle interacting with a harmonic thermal bath

2025/10/22 by Bonetto, Federico, Maiocchi, Alberto Mario
#FOS: Physical sciences #Mathematical Physics (math-ph) #Statistical Mechanics (cond-mat.stat-mech)

paper · doi:10.48550/arxiv.2510.20003

Abstract

We study the long time evolution of the position-position correlation function Cα,N(s,t) for a harmonic oscillator (the \it probe) interacting via a coupling α with a large chain of N coupled oscillators (the \it heat bath). At t=0 the probe and the bath are in equilibrium at temperature TP and TB, respectively. We show that for times t and s of the order of N, Cα,N(s,t) is very well approximated by its limit Cα(s,t) as N→∞. We find that, if the frequency Ω of the probe is in the spectrum of the bath, the system appears to thermalize, at least at higher order in α. This means that, at order 0 in α, Cα(s,t) equals the correlation of a probe in contact with an ideal stochastic \it thermostat, that is forced by a white noise and subject to dissipation. In particular we find that limt→∞ Cα(t,t)=TB2 while that limτ→∞ Cα(τ,τ+t) exists and decays exponentially in t. Notwithstanding this, at higher order in α, Cα(s,t) contains terms that oscillate or vanish as a power law in |t-s|. That is, even when the bath is very large, it cannot be thought of as a stochastic thermostat. When the frequency of the bath is far from the spectrum of the bath, no thermalization is observed.

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