2022/12/08 by Batalova, Elizaveta A., Kamaeva, Larisa V., Chtchelkatchev, Nikolay M.
#Chemical Physics (physics.chem-ph) #Computational Physics (physics.comp-ph) #FOS: Physical sciences #Materials Science (cond-mat.mtrl-sci)
paper · doi:10.48550/arxiv.2212.04404
In this work, using the methods of viscosimetry and thermal analysis, the concentration changes in the values of the supercooling viscosity of Al-Mg melts with Mg content from 2.5 to 95 at.% are studied. It is shown that the temperature dependences of viscosity are well described by an exponential dependence. The concentration dependence of viscosity is not monotonous and reflects a change in the chemical short-range order in the liquid phase. The concentration dependence of supercooling of Al-Mg melts is determined by the type of solid phase formed during solidification, and also reflects the most significant changes in the chemical short-range order in the liquid phase at 20 and 80 at.% Mg. Al-Mg alloys in the concentration ranges: 0-10, 40-50 and 90-100 at.% Mg are prone to non-equilibrium crystallization, the formation of quasi-eutectics and solidification without intermediate intermetallic phases.