2026/03/12 by Bruna Gabrielly
#quant-ph #cond-mat.str-el #physics.chem-ph
Valence-bond wavefunctions such as spin-coupled generalized valence bond (SCGVB) provide compact and chemically interpretable descriptions of strong correlation, but their nonorthogonal determinant structure makes quantum evaluation of overlaps and Hamiltonian matrix elements difficult. Here we introduce an ancilla-free, measurement-driven framework that reformulates these quantities as vacuum expectation values of Pauli-string operators, enabling evaluation with shallow circuits, local Clifford rotations, and computational-basis measurements, without controlled operations. We validate the method for H4 along a dissociation pathway and for a 70-determinant C2 active-valence benchmark. The reconstructed matrices agree with the classical Löwdin-based reference, while Chirgwin-Coulson weights remain chemically consistent. These results establish the proposed estimators as a low-depth, circuit-compatible formulation for evaluating SCGVB matrix elements, while making no claim of quantum computational advantage.