Electrical double layer: revisit based on boundary conditions

2005/11/01 by Jong U. Kim, Kim, Jong U.
Chemistry · Physics and Astronomy · #Chemical Physics (physics.chem-ph) #Electrostatics and Colloid Interactions #FOS: Physical sciences #Instrumentation and Detectors (physics.ins-det) #physics.chem-ph #physics.ins-det

paper · pdf · doi:10.48550/arxiv.physics/0511007

Unfortunately, the previous version has a crucial misconcept. It is corrected

openalex publication_date 2005/11/01 · arxiv created 2005/12/11 · arxiv updated 2009/12/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

The electrical double layer at infinite flat solid surface was discussed with respect to the triple layer model. Charge density at the outer Helmholtz plane is assumed to be zero usually. However, the assumption causes the position of the outer Helmholtz plane to be obscure. The charge density was calculated and the condition that the charge density is negligible was discussed.

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