2016/08/29 by S. L. Yakovlev, S L Yakovlev, Yakovlev, S L +9 · 1 citation
Biochemistry, Genetics and Molecular Biology · Materials Science · Mathematics · Physics and Astronomy · #Electron Spin Resonance Studies #Lanthanide and Transition Metal Complexes #Quantum optics and atomic interactions #math-ph #math.MP #physics.atom-ph #quant-ph
paper · pdf · doi:10.48550/arxiv.1608.07957
13 pages
arxiv created 2016/08/29 · arxiv updated 2016/08/30
The multichannel scattering problem in an adiabatic representation is considered. The non-adiabatic coupling matrix is assumed to have a non-trivial constant asymptotic behavior at large internuclear separations. The asymptotic solutions at large internuclear distances are constructed. It is shown that these solutions up to the first order of perturbation theory are identical to the asymptotic solutions of the re-projection approach, which was proposed earlier as a remedy for the electron translation problem in the context of the Born-Oppenheimer treatment.