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Minimal cooling speed for glass transition in a simple solvable energy landscape model

2015/10/12 by J. Quetzalcóatl Toledo-Marín, Toledo-Marín, J. Quetzalcóatl, Isaac Pérez Castillo +3
Physics and Astronomy · #FOS: Physical sciences #Soft Condensed Matter (cond-mat.soft) #Statistical Mechanics (cond-mat.stat-mech) #cond-mat.soft #cond-mat.stat-mech

paper · pdf · doi:10.48550/arxiv.1510.03412

17 pages, 9 figures

arxiv created 2015/10/28 · arxiv updated 2015/10/29

Abstract

The minimal cooling speed required to form a glass is obtained for a simple solvable energy landscape model. The model, made from a two-level system modified to include the topology of the energy landscape, is able to capture either a glass transition or a crystallization depending on cooling rate. In this setup, the minimal cooling speed to achieve glass formation is then found to be related with the relaxation time and with the thermal history. In particular, we obtain that the thermal history encodes small fluctuations around the equilibrium population which are exponentially amplified near the glass transition, which mathematically corresponds to the boundary layer of the master equation. Finally, to verify our analytical results, a kinetic Monte-Carlo simulation was implemented.

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