2007/05/16 by Zwanikken, Jos, van Roij, René
#FOS: Physical sciences #Soft Condensed Matter (cond-mat.soft)
paper · doi:10.48550/arxiv.0705.2327
We study suspensions of hydrophobic charged colloidal spheres dispersed in a demixed oil-water mixture by means of a modified Poisson-Boltzmann theory, taking into account image charge effects and partitioning of the monovalent ions. We find that the ion's aversion for oil can destroy the double layers of the oil-dispersed colloids. This affects the salt-concentration dependence of the colloidal adsorption to the oil-water interface qualitatively. The theory also predicts a narrow range of the oil-dielectric constant in which micron-sized water-in-oil droplets acquire enough charge to crystallize at volume fractions as small as ∼ 10-3 in the absence of colloids. These findings explain recent observations [M.E. Leunissen \em et al., Proc. Nat. Ac. Sci \bf 104, 2585 (2007)].