Empirical electronic polarizabilities of ions for the prediction and interpretation of refractive indices: Oxides and oxysalts

2016/10/01 by Robert D. Shannon, R. D. Shannon, Reinhard X. Fischer +1 · 5 citations
Materials Science · #Crystal Structures and Properties #Luminescence Properties of Advanced Materials #Glass properties and applications

paper · doi:10.2138/am-2016-5730

Abstract

An extensive set of refractive indices determined at λ = 589.3 nm (nD) from ~2600 measurements on 1200 minerals, 675 synthetic compounds, ~200 F-containing compounds, 65 Cl-containing compounds, 500 non-hydrogen-bonded hydroxyl-containing compounds, and ~175 moderately strong hydrogen-bonded hydroxyl-containing compounds and 35 minerals with very strong H-bonded hydroxides was used to obtain mean total polarizabilities. These data, using the Anderson-Eggleton relationship

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