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Extraction of spin-averaged rovibrational transition frequencies in HD+ for the determination of fundamental constants

2022/12/22 by Karr, Jean-Philippe, Koelemeij, Jeroen C. J. · 2 citations
#Atomic Physics (physics.atom-ph) #Data Analysis #FOS: Physical sciences #Statistics and Probability (physics.data-an)

paper · doi:10.48550/arxiv.2212.11683

Abstract

We present a comprehensive analysis of all currently available high-accuracy frequency measurements of rotational and rovibrational transitions in the hydrogen molecular ion HD+. Our analysis utilises the theoretically calculated hyperfine structure to extract the values of three spin-averaged transition frequencies through a global linear least-squares adjustment that takes into account theory-induced correlations between the different transitions. We subsequently use the three spin-averaged transition frequencies as input data in a second adjustment which employs precise theoretical expressions for the transition frequencies, written as a function of the proton, deuteron and electron relative atomic masses, the Rydberg constant, and the proton and deuteron charge radii. Our analysis shows that the HD+ data may significantly improve the value of the electron relative atomic mass and the proton-electron mass ratio, in particular if combined with recent high-precision measurements of particle atomic masses and mass ratios obtained from Penning traps.

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