2023/08/08 by Yinqiao Wang, Wang, Yinqiao, Michio Tateno +3 · 1 citation
Materials Science · #Disordered Systems and Neural Networks (cond-mat.dis-nn) #FOS: Physical sciences #Liquid Crystal Research Advancements #Material Dynamics and Properties #Soft Condensed Matter (cond-mat.soft)
paper · pdf · doi:10.48550/arxiv.2308.04250
openalex publication_date 2023/08/08 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28
Glasses and gels, widely encountered amorphous solids with diverse industrial and everyday applications, share intriguing similarities such as rigidity without crystalline order and dynamic slowing down during aging. However, the underlying differences between these two fascinating materials have remained elusive. Here we uncover distinct elastic properties concerning observation and aging times in glasses and gels, while delving into the underlying mechanisms. In glasses, we observe a gradual decrease in the shear modulus, while the bulk modulus remains constant throughout the observation time. In contrast, gels exhibit a decrease in both the shear and bulk moduli over the observation time. Additionally, during aging, glasses exhibit a steady trend of stiffening, while gels demonstrate initial stiffening followed by softening. By unravelling the intricate relationship between structure, dynamics, and elasticity, we attribute these differences to mechanisms that minimize free energy: structural ordering in glasses and interface reduction in gels. Our work not only uncovers the distinct behaviors of glasses and gels but also sheds light on the origin and evolution of elasticity in non-equilibrium disordered solids, offering significant implications for the application and design of amorphous materials.