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Mn Site Substitution Of La0.67Ca0.33MnO3 With Closed Shell Ions: Effect on Magnetic Transition Temperature

2002/03/21 by L. Seetha Lakshmi, V. Sridharan, Lakshmi, L. Seetha +8
Materials Science · Physics and Astronomy · #Advanced Condensed Matter Physics #FOS: Physical sciences #Magnetic and transport properties of perovskites and related materials #Rare-earth and actinide compounds #Strongly Correlated Electrons (cond-mat.str-el) #cond-mat.str-el

paper · pdf · doi:10.48550/arxiv.cond-mat/0203425

11 pages, 4 figures, To be published in Pramana-international Journal of Physics

arxiv created 2002/03/21 · openalex publication_date 2002/03/21 · arxiv updated 2009/11/30 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

Mn site is substituted with closed shell ions (Al, Ga. Ti, Zr and a certain combination of Zr and Al) and also with Fe and Ru ions carrying the magnetic moment (S=5/2 and 2 respectively) at a fixed concentration of 5 at. %. Substitution did not change either the crystal symmetry or the oxygen stiochiometry. All substituents were found to suppress both the metal-insulator and ferromagnetic transition temperatures (TP(r) and TC respectively) to varied extents. Two main contributions identified for the suppression are the lattice disorder arising due to difference in the ionic radii (rMn3+-rM) between the substituent (rM) and the Mn3+ ion (rMn3+) and in the case of the substituents carrying a magnetic moment, the type of magnetic coupling between the substituent and that of the neighboring Mn ion.

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