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Laser Induced Periodic Surface Crystalline Patterns on SrO-0.5Li2O-4.5B2O3 and BaO-0.5Na2O-4.5B2O3 Glasses and Optical Second Harmonic Generation

2010/07/12 by Rahul Vaish, Vaish, Rahul, Vincent Rodriguez +7
Earth and Planetary Sciences · Materials Science · Physics and Astronomy · #FOS: Physical sciences #Glass properties and applications #Materials Science (cond-mat.mtrl-sci) #Mineralogy and Gemology Studies #Photorefractive and Nonlinear Optics

paper · doi:10.48550/arxiv.1007.1845

openalex publication_date 2010/07/12 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

Transparent SrO-0.5Li2O-4.5B2O3 (SLBO) and BaO-0.5Na2O-4.5B2O3 (BNBO) glasses were fabricated via the conventional melt-quenching technique. The amorphous and glassy characteristics of the as-quenched samples were respectively confirmed by X-ray powder diffraction (XRD) and Differential Thermal Analysis (DTA) studies. Optically clear SLBO and BNBO glass nano/microcrystal composites were obtained by heat-treating the as-quenched glasses slightly above their respective glass transition temperatures. These glass nano/microcrystal composites exhibited second harmonic signals in transmission mode when exposed to infrared laser beam at λ=1064 nm. Interestingly second-harmonic waves were found to undergo optical diffraction and was attributed to the presence of self-organized microcrystalline patterns associated with 0.5-2μm periodicities.

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