2003/06/09 by R. Mahendiran, Mahendiran, R., B. G. Ueland +16
Chemical Engineering · Materials Science · Physics and Astronomy · #Advanced Condensed Matter Physics #Catalysis and Oxidation Reactions #FOS: Physical sciences #Magnetic and transport properties of perovskites and related materials #Materials Science (cond-mat.mtrl-sci) #cond-mat.mtrl-sci
paper · pdf · doi:10.48550/arxiv.cond-mat/0306223
16 pages nad 5 figures
arxiv created 2003/06/09 · openalex publication_date 2003/06/09 · arxiv updated 2009/11/30 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28
We investigate the magnetothermodynamic properties of the perovskite manganite Pr0.46Sr0.54MnO3. Our data imply that the paramagnetic to antiferromagnetic transition at TN = 210 K is first order with an abrupt decrease of volume (~ 0.14 % in zero magnetic field) and is accompanied by a sharp anomaly in specific heat. Upon application of a sufficiently large magnetic field, the antiferromagnetic phase transforms into a ferromagnetic phase with a sharp increase in sample volume. This field induced transition results in a large positive magnetocaloric effect just below TN (∆Sm = 10.4 Jkg-1K-1 at H = 5.5 T), which is associated with the increasing stability of the antiferromagnetic state with decreasing temperature.