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High-entropy ceramics: propelling applications through disorder

2021/11/22 by Toher, Cormac, Oses, Corey, Esters, Marco +6
#FOS: Physical sciences #Materials Science (cond-mat.mtrl-sci)

paper · doi:10.48550/arxiv.2111.11519

Abstract

Disorder enhances desired properties, as well as creating new avenues for synthesizing materials. For instance, hardness and yield stress are improved by solid-solution strengthening, a result of distortions and atomic size mismatches. Thermo-chemical stability is increased by the preference of chemically disordered mixtures for high-symmetry super-lattices. Vibrational thermal conductivity is decreased by force-constant disorder without sacrificing mechanical strength and stiffness. Thus, high-entropy ceramics propel a wide range of applications: from wear resistant coatings and thermal and environmental barriers to catalysts, batteries, thermoelectrics and nuclear energy management. Here, we discuss recent progress of the field, with a particular emphasis on disorder-enhanced properties and applications.

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