2019/04/17 by Souratosh Khan, Khan, Souratosh, S. Mazumdar +1 · 1 citation
Chemistry · Physics and Astronomy · #Advanced Chemical Physics Studies #Advanced NMR Techniques and Applications #Chemical Physics (physics.chem-ph) #FOS: Physical sciences #Quantum, superfluid, helium dynamics #Strongly Correlated Electrons (cond-mat.str-el)
paper · pdf · doi:10.48550/arxiv.1904.08539
openalex publication_date 2019/04/17 · openalex created_date 2022/07/29 · openalex updated_date 2026/07/28
Recent advances in singlet-fission research make it imperative that structure-property correlations that determine optical signatures of the triplet-triplet spin biexciton as well as its binding energy be understood precisely. We report many-body calculations of excited state absorptions from the triplet exciton and the triplet-triplet biexciton from two transversally linked dimers of pentacene derivatives. Comparison of experiment against theory leads to new interpretations of experiments performed earlier. We show that in the para-linked isomer the triplet-triplet does not dissociate to free triplets through the duration of the measurements. In contrast, even as calculated and experimental transient absorptions agree in the meta-isomer, the experimental observations here are more difficult to interpret, indicating the strong role structural variations can play in determining the rate and yield of free triplets. We also report many-body calculations of the spin gap, the energy difference between the spin quintet versus spin singlet triplet-triplet, as well as the binding energy of the spin singlet triplet-triplet, defined as the energy difference between two free triplets and the bound biexciton. The spin gap and the binding energy of the spin singlet triplet-triplet are different quantities in all but coupled two-level systems. The experimental behavior in the transversally linked dimers as well as previously studied longitudinally linked dimers agree with the trends that would be predicted from the computed biexciton binding energies.