Atomic polarizabilities and shielding factors

1962/10/01 by A. Dalgarno · 4 citations
Physics and Astronomy · #Advanced Chemical Physics Studies #Atomic and Molecular Physics #X-ray Spectroscopy and Fluorescence Analysis

paper · doi:10.1080/00018736200101302

Abstract

Abstract A detailed discussion is given of the methods of calculating atomic polarizabilities and shielding factors and the relationships between them are demonstrated. The formulation of the uncoupled Hartree-Fock approximation is presented and it is shown that the methods are all approximate versions of it. A more accurate procedure, the coupled Hartree-Fock approximation, is described. Comprehensive tables of dipole and quadrupole polarizabilities and of quadrupole shielding factors are included together with an assessment of the probable accuracy.

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