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Electron energy loss spectra of Na0.33CoO2.yH2O (y = 0, 0.6 and 1.3)

2004/12/30 by J.Q. Li, J. Q. Li, H. X. Yang +12
Energy · Materials Science · Physics and Astronomy · #Electrocatalysts for Energy Conversion #Electron and X-Ray Spectroscopy Techniques #FOS: Physical sciences #Strongly Correlated Electrons (cond-mat.str-el) #Superconductivity (cond-mat.supr-con) #TiO2 Photocatalysis and Solar Cells #cond-mat.str-el #cond-mat.supr-con

paper · pdf · doi:10.48550/arxiv.cond-mat/0412753

19 pages, 5 figures

arxiv created 2004/12/30 · openalex publication_date 2004/12/30 · arxiv updated 2009/12/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

Electron energy loss (EEL) spectra have been obtained on materials with the nominal compositions of Na0.33CoO2yH2O (y = 0, 0.6 and 1.3). Spectral analyses revealed systematic changes in the low-loss energy region (< 10eV) and the core losses(O-K, Co-L3,2) along with the water intercalation. The inter (intra)-band transitions and the relevant plasmon resonance were found to be sensitive to water content. Variations of the electronic structure and the Co valence states during hydration have been discussed based on our experimental results.

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