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Screening of hydrodynamic interactions for polyelectrolytes in salt solution

2008/09/30 by Jens Smiatek, Friederike Schmid, Smiatek, Jens +1
Chemistry · Physics and Astronomy · #Electrostatics and Colloid Interactions #FOS: Physical sciences #Soft Condensed Matter (cond-mat.soft) #Surfactants and Colloidal Systems #cond-mat.soft

paper · pdf · doi:10.48550/arxiv.0809.5239

4 pages, 4 figures, submitted to Physical Review Letters

arxiv created 2008/09/30 · openalex publication_date 2008/09/30 · arxiv updated 2009/12/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

We provide numerical evidence that hydrodynamic interactions are screened for charged polymers in salt solution on time scales below the Zimm time. At very short times, a crossover to hydrodynamic behavior is observed. Our conclusions are drawn from extensive coarse-grained computer simulations of polyelectrolytes in explicit solvent and explicit salt, and discussed in terms of analytical arguments based on the Debye-Hueckel approximation.

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