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A coarse grained model of polymer networks focusing on the intermediate length scales

2008/03/29 by Takashi Shibata, Shibata, Takashi, Hidemitsu Furukawa +3
Chemistry · Physics and Astronomy · #Advanced Polymer Synthesis and Characterization #FOS: Physical sciences #Soft Condensed Matter (cond-mat.soft) #cond-mat.soft

paper · pdf · doi:10.48550/arxiv.0803.4237

9 pages, 4 figures,

arxiv created 2008/03/29 · openalex publication_date 2008/03/29 · arxiv updated 2009/12/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

We propose a coarse-grained model for polymer chains and polymer networks based on the meso-scale dynamics. The model takes the internal degrees of freedom of the constituent polymer chains into account using memory functions and colored noises. We apply our model to dilute polymer solutions and polymer networks. A numerical simulation on a dilute polymer solution demonstrates the validity of the assumptions on the dynamics of our model. By applying this model to polymer networks, we find a transition in the dynamical behavior from an isolated chain state to a network state.

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