2006/04/07 by R. J. Radwański, R. J. Radwanski, Radwanski, R. J. +2
Chemistry · Materials Science · Physics and Astronomy · #FOS: Physical sciences #Inorganic Chemistry and Materials #Magnetism in coordination complexes #Rare-earth and actinide compounds #Strongly Correlated Electrons (cond-mat.str-el) #cond-mat.str-el
paper · pdf · doi:10.48550/arxiv.cond-mat/0604207
2 pages, 2 figures embedded
arxiv created 2006/04/07 · openalex publication_date 2006/04/07 · arxiv updated 2009/12/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28
In contrary to customarily consideration of the Jahn-Teller theorem for 3d-ion compounds in the orbital space only we point out that it has to be considered in the spin-orbital space. It is despite the weakness of the intraatomic spin-orbit coupling. A direct motivation for this paper is an erroneous claim of a recent Phys. Rev. Lett. 96 (2006) 027201 paper that the high-spin t2g4eg2 state of the 3d6 configuration is not Jahn-Teller active.