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Surface Saturation Current Densities of Perovskite Thin Films from Suns-Photoluminescence Quantum Yield Measurements

2023/06/07 by Chin, Robert Lee, Soufiani, Arman Mahboubi, Fassl, Paul +6
#Applied Physics (physics.app-ph) #FOS: Physical sciences #Optics (physics.optics)

paper · doi:10.48550/arxiv.2306.04194

Abstract

We present a simple, yet powerful analysis of Suns-photoluminescence quantum yield measurements that can be used to determine the surface saturation current densities of thin film semiconductors. We apply the method to state-of-the-art polycrystalline perovskite thin films of varying absorber thickness. We show that the non-radiative bimolecular recombination in these samples originates from the surfaces. To the best of our knowledge, this is the first study to demonstrate and quantify non-linear (bimolecular) surface recombination in perovskite thin films.

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