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Enhanced magnetism, memory and aging in Gold-Iron oxide nanoparticle composites

2009/06/08 by S. Banerjee, Soumitro Banerjee, Banerjee, S. +12 · 1 citation
Biochemistry, Genetics and Molecular Biology · Engineering · Materials Science · Physics and Astronomy · #Characterization and Applications of Magnetic Nanoparticles #FOS: Physical sciences #Geomagnetism and Paleomagnetism Studies #Magnetic Properties and Synthesis of Ferrites #Materials Science (cond-mat.mtrl-sci) #cond-mat.mtrl-sci

paper · pdf · doi:10.48550/arxiv.0906.1497

12 figures, 33 pages total

openalex publication_date 2009/06/08 · arxiv created 2009/10/26 · arxiv updated 2009/12/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

In this report we present systematic magnetic studies of pure iron oxide nanoparticles and gold iron oxide nanocomposite with increasing Au particle size/content. For the magnetic studies of these samples we have measured: (1) zero field cooled (ZFC) and field cooled (FC) magnetization, (2) ac susceptibility, (3) magnetization vs field at various temperatures, (4) thermoremanant magnetization relaxation (TRM) and zero field cooled magnetization relaxation (ZFCM) at fixed temperature for various wait times tw for studying the aging effect, (5) magnetization memory effect and (6) exchange bias as a function of cooling field. The detailed magnetic measurement analysis indicates that the pure Fe3O4 nanoparticles sample behaves like a superparamagnet and on incorporation of gold (Au) nanoparticles the nanocomposite system slowly evolves from superparamagnetic to superspin glass state. The memory and aging effect enhances with the increase of the Au nanoparticle size/content. The most important observation in this study is the enhancement of magnetization with the incorporation of Au nanoparticles. The enhancement increases with the increase in the Au content in the nanocomposite. We have explained the cause of this enhancement of magnetization as due to large orbital magnetic moment formation at the Au/magnetic particle interface.

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