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Cation and anion substitutions in hybrid perovskites: solubility limits and phase stabilizing effects

2018/10/16 by Frederike Lehmann, Lehmann, Frederike, Silvia Binet +7
Engineering · Materials Science · Physics and Astronomy · #Chalcogenide Semiconductor Thin Films #Conducting polymers and applications #FOS: Physical sciences #Materials Science (cond-mat.mtrl-sci) #Perovskite Materials and Applications #Solid-state spectroscopy and crystallography #cond-mat.mtrl-sci

paper · pdf · doi:10.48550/arxiv.1810.07108

4 pages, 3 figures, 2018 IEEE 45th Photovoltaic Specialists Conference

arxiv created 2018/10/16 · openalex publication_date 2018/10/16 · arxiv updated 2018/10/17 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

Organic or inorganic (A) metal (M) halide (X) perovskites (AMX3) are semiconductor materials setting the basis for the development of highly efficient, low-cost and multijunction solar energy conversion devices. The best efficiencies nowadays are obtained with mixed compositions containing methylammonium, formamidinium, Cs and Rb as well as iodine, bromine and chlorine as anions. The understanding of fundamental properties such as crystal structure and its effect on the band gap, as well as their phase stability is essential. In this systematic study X-ray diffraction and photoluminescense spectroscopy were applied to evaluate structural and optoelectronic properties of hybrid perovskites with mixed compositions.

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