1988/01/01 by Stahlberg, Brigitte, Mosel, Bernd D., W. Müller‐Warmuth +3
Engineering · Materials Science · #660 #Glass properties and applications #Nuclear materials and radiation effects #Recycling and utilization of industrial and municipal waste in materials production
paper · doi:10.34657/14267
openalex publication_date 1988/01/01 · openalex created_date 2016/09/16 · openalex updated_date 2026/07/01
The antimony redox equilibrium in an oxide glass-forming melt has been studied quantitatively. Oxygen fugacities at various concentrations and temperatures have been measured electrochemically, and Sb3+/Sb5+ concentration ratios were determined by Mössbauer spectroscopy. Equilibrium constants K(T) and thermodynamie standard values are given for the redox reaction in the melt at temperatures between 1000 and 1500 °C. If KT) is known, the progress of redox fining can be followed by measuring only the oxygen fugacity.