2024/07/28 by Matthew S. Cook, Cook, Matthew S., David C. Arellano +9
Engineering · Materials Science · Physics and Astronomy · #FOS: Physical sciences #Intermetallics and Advanced Alloy Properties #Materials Science (cond-mat.mtrl-sci) #Metallurgical and Alloy Processes #Rare-earth and actinide compounds #Strongly Correlated Electrons (cond-mat.str-el)
paper · pdf · doi:10.48550/arxiv.2407.19581
openalex publication_date 2024/07/28 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28
We present the ab initio supported discovery of two new Pu based intermetallic compounds, PuNiSn and PuPtSn. Using density functional theory, the formation energies within the relevant ternary phase diagrams were calculated to predict the stability of both compounds. Simultaneously, Pu-Ni-Sn and Pu-Pt-Sn materials were arc-melted and subsequently characterized with magnetization, specific heat, and resistivity measurements from 2-300 K. Magnetization measurements show that PuNiSn and PuPtSn order antiferromagnetically at TN = 11 K and TN = 15 K, respectively. Specific heat measurements show an enhanced residual electronic specific heat that is indicative of strong electron correlations. Resistivity measurements are indicative of Kondo behavior for PuNiSn while crystal field effects may play a role in the observed temperature dependence for PuPtSn.