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Study of the SmBaCuO solid solutions decomposition and its possible role for changing critical current

2004/01/16 by Н. И. Мацкевич, N. I. Matskevich, Matskevich, N. I. +9
Materials Science · Physics and Astronomy · #Advanced Condensed Matter Physics #FOS: Physical sciences #Magnetic and transport properties of perovskites and related materials #Materials Science (cond-mat.mtrl-sci) #Physics of Superconductivity and Magnetism #Superconductivity (cond-mat.supr-con) #cond-mat.mtrl-sci #cond-mat.supr-con

paper · pdf · doi:10.48550/arxiv.cond-mat/0401277

8 pages, 2 figures

arxiv created 2004/01/16 · openalex publication_date 2004/01/16 · arxiv updated 2009/12/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

We studied thermochemical characteristics of the Sm1+xBa2-xCu3Oy single crystals by solution calorimetry. Dependences of formation enthalpies from samarium content were constructed. It was established that solid solutions on the bases of Sm123 could be decomposed both in inert and in oxygen atmosphere into different mixtures. We supposed that solid solutions decomposition could lead to increasing critical current density. We assumed from thermochemical data that Jc could be greater for samples prepared in oxygen than for samples synthesized in inert atmosphere. We confirmed these assumptions by comparison of obtained thermochemical data with transport properties measured in literature. We also investigated temperature dependences of resistance in the temperature range of 300-550 K during slow heating. As it was shown there was anomaly of resistance near 500 K. The origin of this anomaly was discussed.

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