2021/05/11 by Muhammad Gaffar, Gaffar, Muhammad, Sasfan Arman Wella +2
Materials Science · Physics and Astronomy · #Advanced Thermoelectric Materials and Devices #Topological Materials and Phenomena #Graphene research and applications
paper · pdf · doi:10.48550/arxiv.2105.05211
Two-dimensional (2D) bismuth (Bi) layer, known as bismuthene, exhibits Z2 topological bulk states due to large spin-orbit coupling that inverts the bands. Using the tight-binding method, we calculate the band structure of buckled bismuthene to understand its topological and trivial phases. We determine the thermoelectric properties for some considered phases, incorporating the edge states contribution, by using the linearized Boltzmann transport equation (BTE) with a constant relaxation time approximation. It is shown that the thermoelectric figure of merit, ZT, actually drops in undoped topological bismuthene due to the edge effects. Surprisingly, the topological edge states enhance ZT at large doping with the Fermi energy near the bottom of bulk bands when bismuthene is nearly metallic.