2025/09/23 by Osorio, Alam, Lucia Reining, Francesco Sottile +2
Chemistry · Materials Science · #Boron and Carbon Nanomaterials Research #FOS: Physical sciences #Graphene research and applications #Materials Science (cond-mat.mtrl-sci) #Organoboron and organosilicon chemistry
paper · pdf · doi:10.48550/arxiv.2509.19106
openalex publication_date 2025/09/23 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28
Borophene is a two-dimensional material made out of boron atoms only. It exhibits polymorphism and different allotropes can be studied in terms of a rigid electronic structure, where only the occupation of the states change with the respect to the number of electrons available in the system (self-doping). In this work we selected a set of representative borophene polymorphs (δ3, δ5, δ6, β12 α1, α', α'-Bilayer) and studied the shared features of their electronic structures and the limitations of this model. Our work revealed the appearance of defect-like states in some polymorphs when related to a parent rigid electronic structure, and bonding/antibonding monolayer-like states in the α'-Bilayer. Moreover, we show how the buckling of δ6 and α' can act as a tuning parameter, enabling semimetallicity, Dirac cones, and nesting of the Fermi surface. In light of their promises for exotic but also useful behavior, we expect our work to foster the interest in larger and more complex borophene structures.