1994/04/30 by Simeon Warner, Warner, Simeon
Physics and Astronomy · #Condensed Matter (cond-mat) #FOS: Physical sciences #cond-mat
paper · pdf · doi:10.48550/arxiv.cond-mat/9404102
171 pages, latex. PhD Thesis, Dept. of Physics, University of Manchester, UK (April 1994)
arxiv created 2000/05/16 · arxiv updated 2009/11/30
The work to be described falls into three parts: (1) The computer-controlled CW spectrometer was designed to supplement the Manchester pulsed microwave spectrometer in situations where rapid nuclear relaxation makes spin-echo spectroscopy difficult. Its operating range is 4-8 GHz. Resonator designs and modulation strategies will be discussed in the light of practical experience. (2) Both CW and pulsed NMR have been used to study the field dependence of the hyperfine splittings of 165Ho in HoF3 and, as a dilute substituent, in YF3. The low site symmetry results in a singlet crystal-field ground state for the Ho3+ ion, giving Van Vleck paramagnetism and enhanced nuclear magnetism at low temperatures. The measurements were made at temperatures in the range 1.5 to 4.2 K and in fields of up to 8 T. This work has revealed, for the first time, distinct spectra from the two subtly inequivalent rare-earth sites in the orthorhombic unit cell. Because of the non-colinear spin structure of HoF3, the NMR and magnetometry measurements give independent and complimentary information about the ionic moments. (3) The measured hyperfine splittings have been interpreted in terms of a 15-parameter crystal-field Hamiltonian appropriate to the C1h site symmetry. This work has entailed a substantial effort to clarify the notational confusion that exists in the literature. A computer program has been developed to automate conversion between notational conventions prior to diagonalization of the 136-dimensional electronic-nuclear Hamiltonian comprising the Zeeman, crystal-field and hyperfine interactions. [abridged]