X-ray photoelectron 3s spectra of transition metal oxides

1999/03/23 by V. R. Galakhov, Galakhov, V. R., St. Uhlenbrock +18
Materials Science · Physics and Astronomy · #Electron and X-Ray Spectroscopy Techniques #FOS: Physical sciences #Materials Science (cond-mat.mtrl-sci) #X-ray Diffraction in Crystallography #cond-mat.mtrl-sci

paper · pdf · doi:10.48550/arxiv.cond-mat/9903354

17 pages with 9 embedded postscript figures, uses ioplppt.sty

arxiv created 1999/03/23 · openalex publication_date 1999/03/23 · arxiv updated 2009/11/30 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

We present metal 3s x-ray photoelectron spectra of different transition metal oxides. The values of the 3s exchange splitting for the 3d metal oxides are given as a function of the 3d electron number in the ground state. The spectra were analysed using the simple two-configuration model of the interatomic configuration mixing. The change of the 3s spectra is ascribed to the change of the charge-transfer energy.

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