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Experimental determination of the sodium K-shell atomic fundamental parameters for X-ray spectroscopy

2025/06/17 by Marie-Louis Venzke, Venzke, Marie-Louis, Katja Frenzel +3 · 1 citation
Materials Science · Physics and Astronomy · #X-ray Diffraction in Crystallography #X-ray Spectroscopy and Fluorescence Analysis #Nuclear Physics and Applications

paper · pdf · doi:10.48550/arxiv.2506.14352

Abstract

Reliable fundamental parameters are essential for accurate X-ray fluorescence analysis of sodium. This work presents updated experimental values with reliable uncertainties for sodium K-shell fundamental parameters such as: fluorescence yield, photoionization cross sections, and Auger yields. Using a physically calibrated setup and a thin NaCl layer on a silicon nitride membrane, a holistic determination approach was applied to reduce uncertainties. The new values represent a significant improvement on the ones widely used in databases. All data are available via Zenodo to support precise sodium quantification in scientific and industrial applications.

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